The charge pressure in your tank is based on the fill pressure or operating pressure of the system where the tank is located. In a chilled water system operating at 45ºF, the tank only comes into play when the system warms up to room or ambient temperature.
To recharge the tank, isolate it from the system, break the connection between the tank and the system shut-off valve, and allow the water in the tank to drain.
Once all the water is out of the bladder, you can start charging the air/nitrogen side of the tank. The tank cannot be properly charged with water in the bladder. If the tank had lost its air charge, water will expel as you add air/nitrogen to the tank. Once the water is out and the charge is increased, you can soap up the end of the water pipe from the tank to see if any air/nitrogen is leaking out. If a drain has been installed at the bottom of the tank with a valve, remove the valve and piping and install a pipe plug. If the nitrogen line is connected to the side of the tank with a valve, I would recommend soaping the valve to see if there are any air leaks. You might want to check all the fittings with a soap solution.